Cobalt Loading Effects on the Physico-Chemical Properties and Performance of Co Promoted Alkalized MoS2/CNTs Catalysts for Higher Alcohols Synthesis
نویسندگان
چکیده مقاله:
An extensive study of Higher Alcohol Synthesis (HAS) from synthesis gas using cobalt (Co) promoted alkalized MoS2 catalysts supported on Carbon NanoTubes (CNTs) is reported. Up to 5wt.% of Co is added to the 15wt.% Mo-wt.%K/ CNTs by incipient wetness impregnation method. Most of the metal particles were homogeneously distributed inside the tubes and the rest on the outer surface of the CNTs. The catalysts are extensively characterized by different methods and the activity and selectivity of the catalysts were assessed in a fixed bed micro-reactor. Temperature Programmed Reduction (TPR) tests showed that addition of cobalt decreased the second TPR peak temperature from 801 to 660oC. The diffraction peaks that represent the characteristic K-Mo-O phase (i.e. K2Mo2O7, K2MoO4, K2Mo7O20, KMo4O6, and K0.33MoO3; these species can enhances formation of higher alcohols) were observed in the X- Ray Diffraction (XRD) patterns of unpromoted Mo-K/CNTs and to a greater extent in the XRD patterns of Co-promoted Mo-K/CNTs catalysts. Co addition to Mo-K/CNTs not only increased the number of surface sites, but also decreased the average active metal particle sizes from 7.53 to 5.33 nm and increased the percentage dispersion from 51.1 to 68.2%. Among the catalysts with different Co loadings, catalyst with 5 wt.% Co showed the highest %CO conversion of 38.8%. The total alcohol selectivity reached a maximum of 59.7 wt.% on the catalyst promoted with 3 wt.% cobalt. The catalyst with 3 wt.% Co exhibited selectivity of 41.65 wt.% towards higher alcohols.
منابع مشابه
cobalt loading effects on the physico-chemical properties and performance of co promoted alkalized mos2/cnts catalysts for higher alcohols synthesis
an extensive study of higher alcohol synthesis (has) from synthesis gas using cobalt (co) promoted alkalized mos2 catalysts supported on carbon nanotubes (cnts) is reported. up to 5wt.% of co is added to the 15wt.% mo-wt.%k/ cnts by incipient wetness impregnation method. most of the metal particles were homogeneously distributed inside the tubes and the rest on the outer surface of the cnts. t...
متن کاملMolybdenum Loading Effects on the Physico-Chemical Properties and Performance of Carbon Nanotubes Supported Alkalized MoS2 Catalysts for Higher Alcohols Synthesis
An extensive study of Higher Alcohols Synthesis (HAS) from syngas using alkalized MoS2 catalysts supported on Carbon Nanotubes (CNTs) is reported. Up to 30wt.% of Mo and 8wt.% K are added to the CNTs by impregnation method. The catalysts were characterized by different methods and the performance of the catalysts was assessed in a micro-reactor. TEM images showed that mo...
متن کاملmolybdenum loading effects on the physico-chemical properties and performance of carbon nanotubes supported alkalized mos2 catalysts for higher alcohols synthesis
an extensive study of higher alcohols synthesis (has) from syngas using alkalized mos2 catalysts supported on carbon nanotubes (cnts) is reported. up to 30wt.% of mo and 8wt.% k are added to the cnts by impregnation method. the catalysts were characterized by different methods and the performance of the catalysts was assessed in a micro-reactor. tem images showed that most of the metal particle...
متن کاملEffects of Different Loadings of Ru and Re on Physico-Chemical Properties and Performance of 15% Co/Al2O3 FTS Catalysts
An extensive study of Fischer-Tropsch synthesis (FTS) on alumina-supported cobalt catalysts promoted with different amounts of ruthenium and rhenium is reported. Up to 2 wt% of promoters, are added to the catalyst by coimpregnation. The catalysts are characterized by different methods including: BET physisorption, X-ray diffraction, hydrogen chemisorption, and temperature-programmed reducti...
متن کاملthe effects of planning on accuracy and complexity of iranian efl students’ written narrative task performance
this study compared the different effects of form-focused guided planning vs. meaning-focused guided planning on iranian pre-intermediate students’ task performance. the study lasted for three weeks and concentrated on eight english structures. forty five pre-intermediate iranian students were randomly assigned to three groups of guided planning focus-on-form group (gpfg), guided planning focus...
15 صفحه اولCobalt Loading Effects on the Structure and Activity for Fischer-Tropsch and Water-Gas Shift Reactions of Co/Al2O3 Catalysts
An extensive study of Fischer-Tropsch synthesis (FTS) on alumina-supported cobalt catalysts with different amounts of cobalt is reported. Up to 40 wt % of cobalt, is added to the catalysts by impregnation method. The effect of the cobalt loading on the reducibility of the cobalt oxide species, dispersion of the cobalt, average clusters size, water-gas shift (WGS) activity and activity and s...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ذخیره در منابع من قبلا به منابع من ذحیره شده{@ msg_add @}
عنوان ژورنال
دوره 32 شماره 1
صفحات 21- 29
تاریخ انتشار 2013-03-01
با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023